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Benzylic Ammonium Ylide Mediated Epoxidations
A high yielding synthesis of stilbene oxides using ammonium ylides has been developed. It turned out that the amine leaving group plays a crucial role as trimethylamine gives higher yields than DABCO or quinuclidine. The amine group also influences the diastereoselectivity, and detailed DFT calculat...
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| Udgivet i: | Synlett |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5068558/ https://ncbi.nlm.nih.gov/pubmed/27766017 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0035-1562344 |
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