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Benzylic Ammonium Ylide Mediated Epoxidations

A high yielding synthesis of stilbene oxides using ammonium ylides has been developed. It turned out that the amine leaving group plays a crucial role as trimethylamine gives higher yields than DABCO or quinuclidine. The amine group also influences the diastereoselectivity, and detailed DFT calculat...

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Detalles Bibliográficos
Publicado en:Synlett
Main Authors: Roiser, Lukas, Robiette, Raphaël, Waser, Mario
Formato: Artigo
Idioma:Inglês
Publicado: 2016
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5068558/
https://ncbi.nlm.nih.gov/pubmed/27766017
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0035-1562344
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