Large Hyperpolarizabilities at Telecommunication-Relevant Wavelengths in Donor–Acceptor–Donor Nonlinear Optical Chromophores

[Image: see text] Octopolar D(2)-symmetric chromophores, based on the MPZnM supermolecular motif in which (porphinato)zinc(II) (PZn) and ruthenium(II) polypyridyl (M) structural units are connected via ethyne linkages, were synthesized. These structures take advantage of electron-rich meso-arylporph...

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Detalhes bibliográficos
Publicado no:ACS Cent Sci
Main Authors: Nayak, Animesh, Park, Jaehong, De Mey, Kurt, Hu, Xiangqian, Duncan, Timothy V., Beratan, David N., Clays, Koen, Therien, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2016
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5200929/
https://ncbi.nlm.nih.gov/pubmed/28058285
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.6b00291
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