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The Roles of Molecular Structure and Effective Optical Symmetry in Evolving Dipolar Chromophoric Building Blocks to Potent Octopolar NLO Chromophores

A series of mono-, bis-, tris-, and tetrakis-(porphinato)zinc(II) (PZn)-elaborated ruthenium(II) bis(terpyridine) (Ru) complexes has been synthesized in which an ethyne unit connects the macrocycle meso carbon atom to terpyridyl (tpy) 4-, 4′-, and 4″- positions. These supermolecular chromophores, ba...

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Detalhes bibliográficos
Main Authors: Ishizuka, Tomoya, Sinks, Louise E., Song, Kai, Hung, Sheng-Ting, Nayak, Animesh, Clays, Koen, Therien, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3051192/
https://ncbi.nlm.nih.gov/pubmed/21322603
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105004k
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