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Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines from Terminal Allenes
A copper-catalyzed, chemoselective hydrometalation process enables the use of simple allenes as allylmetal nucleophile surrogates in imine allylation reactions. By modulation of the nitrogen-protecting group, either highly branched- or linear-selective addition can be achieved from the same allene....
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2016
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5198719/ https://ncbi.nlm.nih.gov/pubmed/27723269 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608446 |
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