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Redox-Neutral Aromatization of Cyclic Amines: Mechanistic Insights and Harnessing of Reactive Intermediates for Amine α- and β-C–H Functionalization

Cyclic amines such as pyrrolidine and piperidine are known to undergo condensations with aldehydes to furnish pyrrole and pyridine derivatives, respectively. A combined experimental and computational study provides detailed insights into the mechanism of pyrrole formation. A number of reactive inter...

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Vydáno v:Chemistry
Hlavní autoři: Ma, Longle, Paul, Anirudra, Breugst, Martin, Seidel, Daniel
Médium: Artigo
Jazyk:Inglês
Vydáno: 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5193247/
https://ncbi.nlm.nih.gov/pubmed/27712000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201603839
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