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Formation of hybrid guanidine-stabilized bis(μ-oxo)dicopper cores in solution: Electronic and steric perturbations
A series of new hybrid peralkylated-amine-guanidine ligands based on a 1,3-propanediamine backbone and their Cu-O(2) chemistry is reported. The copper(I) complexes react readily with O(2) at low temperatures in aprotic solvents with weakly coordinating anions to form exclusively bis(μ-oxo) dicopper...
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| Veröffentlicht in: | Eur J Inorg Chem |
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| Hauptverfasser: | , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5158105/ https://ncbi.nlm.nih.gov/pubmed/27990098 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201500884 |
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