Direct visualization of a Fe(IV)–OH intermediate in a heme enzyme

Catalytic heme enzymes carry out a wide range of oxidations in biology. They have in common a mechanism that requires formation of highly oxidized ferryl intermediates. It is these ferryl intermediates that provide the catalytic engine to drive the biological activity. Unravelling the nature of the...

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Udgivet i:Nat Commun
Main Authors: Kwon, Hanna, Basran, Jaswir, Casadei, Cecilia M., Fielding, Alistair J., Schrader, Tobias E., Ostermann, Andreas, Devos, Juliette M., Aller, Pierre, Blakeley, Matthew P., Moody, Peter C. E., Raven, Emma L.
Format: Artigo
Sprog:Inglês
Udgivet: Nature Publishing Group 2016
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5141285/
https://ncbi.nlm.nih.gov/pubmed/27897163
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13445
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