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Addition of Carbon–Fluorine Bonds to a Mg(I)–Mg(I) Bond: An Equivalent of Grignard Formation in Solution
[Image: see text] Addition of the carbon–fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg–Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon–magnesium bond and a new fluorine–magnesium bond...
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| Gepubliceerd in: | J Am Chem Soc |
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| Hoofdauteurs: | , , |
| Formaat: | Artigo |
| Taal: | Inglês |
| Gepubliceerd in: |
American Chemical
Society
2016
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| Online toegang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5135227/ https://ncbi.nlm.nih.gov/pubmed/27636244 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08104 |
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