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Reversible alkene binding and allylic C–H activation with an aluminium(i) complex
The monomeric molecular aluminium(i) complex 1 [{(ArNCMe)(2)CH}Al] (Ar = 2,6-di-iso-propylphenyl) reacts with a series of terminal and strained alkenes including ethylene, propylene, allylbenzene and norbornene to form alkene bound products. Remarkably all these reactions are reversible under mild c...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6388093/ https://ncbi.nlm.nih.gov/pubmed/30881673 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04865g |
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