A carregar...
α,β‐Unsaturated Gold(I) Carbenes by Tandem Cyclization and 1,5‐Alkoxy Migration of 1,6‐Enynes: Mechanisms and Applications
1,6‐Enynes bearing OR groups at the propargyl position generate α,β‐unsaturated gold(I)‐carbenes/ gold(I) stabilized allyl cations that can be trapped by alkenes to form cyclopropanes or 1,3‐diketones to give products of α‐alkylation. The best migrating group is p‐nitrophenyl ether, which leads to t...
Na minha lista:
| Publicado no: | Chemistry |
|---|---|
| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2016
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5132047/ https://ncbi.nlm.nih.gov/pubmed/27527611 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201602347 |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|