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Gold(I) Carbenoids: On‐Demand Access to Gold(I) Carbenes in Solution
Chloromethylgold(I) complexes of phosphine, phosphite, and N‐heterocyclic carbene ligands are easily synthesized by reaction of trimethylsilyldiazomethane with the corresponding gold chloride precursors. Activation of these gold(I) carbenoids with a variety of chloride scavengers promotes reactivity...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
John Wiley and Sons Inc.
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5324612/ https://ncbi.nlm.nih.gov/pubmed/28090747 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611705 |
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