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Gold(I) Carbenoids: On‐Demand Access to Gold(I) Carbenes in Solution
Chloromethylgold(I) complexes of phosphine, phosphite, and N‐heterocyclic carbene ligands are easily synthesized by reaction of trimethylsilyldiazomethane with the corresponding gold chloride precursors. Activation of these gold(I) carbenoids with a variety of chloride scavengers promotes reactivity...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5324612/ https://ncbi.nlm.nih.gov/pubmed/28090747 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201611705 |
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