Asymmetric Induction by a Nitrogen (14)N/(15)N Isotopomer in Conjunction with Asymmetric Autocatalysis

Chirality arising from isotope substitution, especially with atoms heavier than the hydrogen isotopes, is usually not considered a source of chirality in a chemical reaction. An N (2) ,N (2) ,N (3) ,N (3)‐tetramethyl‐2,3‐butanediamine containing nitrogen ((14)N/(15)N) isotope chirality was synthesiz...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Matsumoto, Arimasa, Ozaki, Hanae, Harada, Shunya, Tada, Kyohei, Ayugase, Tomohiro, Ozawa, Hitomi, Kawasaki, Tsuneomi, Soai, Kenso
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5132014/
https://ncbi.nlm.nih.gov/pubmed/27754589
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608955
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