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Asymmetric autocatalysis induced by meteoritic amino acids with hydrogen isotope chirality

Achiral meteoritic amino acids, glycine and α-methylalanine, with hydrogen isotope (D/H) chirality, acted as the source of chirality in asymmetric autocatalysis with amplification of ee to afford highly enantioenriched 5-pyrimidyl alkanols.

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Detalhes bibliográficos
Main Authors: Kawasaki, Tsuneomi, Shimizu, Masako, Nishiyama, Daisuke, Ito, Masateru, Ozawa, Hitomi, Soai, Kenso
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2898652/
https://ncbi.nlm.nih.gov/pubmed/19597604
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b908754k
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