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Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis
Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysi...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2898645/ https://ncbi.nlm.nih.gov/pubmed/19753377 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b912813a |
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