Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis

Chiral isotactic polystyrenes induce the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, affording the enantiomerically enriched pyrimidyl alkanol with the corresponding absolute configuration to that of cryptochiral polystyrenes in conjunction with asymmetric autocatalysi...

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Main Authors: Kawasaki, Tsuneomi, Hohberger, Christiane, Araki, Yuko, Hatase, Kunihiko, Beckerle, Klaus, Okuda, Jun, Soai, Kenso
Format: Artigo
Jezik:Inglês
Izdano: Royal Society of Chemistry 2009
Teme:
Chemistry
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2898645/
https://ncbi.nlm.nih.gov/pubmed/19753377
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/b912813a
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