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Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms

Primary copper(I)-dioxygen (O(2)) adducts, cupric-superoxide complexes, have been proposed intermediates in copper-containing dioxygen-activating monooxygenase and oxidase enzymes. Here, mechanisms of C–H activation by reactive copper-(di)oxygen intermediates are discussed, with an emphasis on cupri...

Täydet tiedot

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Bibliografiset tiedot
Julkaisussa:Isr J Chem
Päätekijät: Liu, Jeffrey J., Diaz, Daniel E., Quist, David A., Karlin, Kenneth D.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2016
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC5125784/
https://ncbi.nlm.nih.gov/pubmed/27909346
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ijch.201600025
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