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Rapid Synthesis of Redox-Active Dodecaborane B(12)(OR)(12) Clusters Under Ambient Conditions
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the closo-[B(12)(OH)(12)](2−) icosahedral dodecaborate cluster via microwave-assisted synthesis. These icosahedral boron clusters exhibit three-dimensional delocalization of the cage...
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| Veröffentlicht in: | Inorg Chem Front |
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| Hauptverfasser: | , , , , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5117651/ https://ncbi.nlm.nih.gov/pubmed/27885335 |
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