Rapid Synthesis of Redox-Active Dodecaborane B(12)(OR)(12) Clusters Under Ambient Conditions

We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the closo-[B(12)(OH)(12)](2−) icosahedral dodecaborate cluster via microwave-assisted synthesis. These icosahedral boron clusters exhibit three-dimensional delocalization of the cage...

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Udgivet i:Inorg Chem Front
Main Authors: Wixtrom, Alex I., Shao, Yanwu, Jung, Dahee, Machan, Charles W., Kevork, Shaunt N., Qian, Elaine A., Axtell, Jonathan C., Khan, Saeed I., Kubiak, Clifford P., Spokoyny, Alexander M.
Format: Artigo
Sprog:Inglês
Udgivet: 2016
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5117651/
https://ncbi.nlm.nih.gov/pubmed/27885335
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