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Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation
We report a new class of redox-active vertex-differentiated dodecaborate clusters featuring pentafluoroaryl groups. These [B(12)(OR)(11)NO(2)] clusters share several unique photophysical properties with their [B(12)(OR)(12)] analogues, while exhibiting significantly higher (+0.5 V) redox potentials....
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| 出版年: | Chem Commun (Camb) |
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| 主要な著者: | , , , , , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2018
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6015501/ https://ncbi.nlm.nih.gov/pubmed/29785419 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc03477j |
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