Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation

We report a new class of redox-active vertex-differentiated dodecaborate clusters featuring pentafluoroaryl groups. These [B(12)(OR)(11)NO(2)] clusters share several unique photophysical properties with their [B(12)(OR)(12)] analogues, while exhibiting significantly higher (+0.5 V) redox potentials....

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Publicat a:Chem Commun (Camb)
Autors principals: Wixtrom, Alex I., Parvez, Zeeshan, Savage, Miles A., Qian, Elaine A., Jung, Dahee, Khan, Saeed I., Rheingold, Arnold L., Spokoyny, Alexander M.
Format: Artigo
Idioma:Inglês
Publicat: 2018
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Article
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC6015501/
https://ncbi.nlm.nih.gov/pubmed/29785419
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8cc03477j
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