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Hydrogenation of CO(2) to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water

The novel [Ru(Acriphos)(PPh(3))(Cl)(PhCO(2))] [1; Acriphos=4,5‐bis(diphenylphosphino)acridine] is an excellent precatalyst for the hydrogenation of CO(2) to give formic acid in dimethyl sulfoxide (DMSO) and DMSO/H(2)O without the need for amine bases as co‐reagents. Turnover numbers (TONs) of up to...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Rohmann, Kai, Kothe, Jens, Haenel, Matthias W., Englert, Ulli, Hölscher, Markus, Leitner, Walter
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5113777/
https://ncbi.nlm.nih.gov/pubmed/27356513
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603878
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