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Hydrogenation of CO(2) to Formic Acid with a Highly Active Ruthenium Acriphos Complex in DMSO and DMSO/Water
The novel [Ru(Acriphos)(PPh(3))(Cl)(PhCO(2))] [1; Acriphos=4,5‐bis(diphenylphosphino)acridine] is an excellent precatalyst for the hydrogenation of CO(2) to give formic acid in dimethyl sulfoxide (DMSO) and DMSO/H(2)O without the need for amine bases as co‐reagents. Turnover numbers (TONs) of up to...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
John Wiley and Sons Inc.
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5113777/ https://ncbi.nlm.nih.gov/pubmed/27356513 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603878 |
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