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The Phenol-ene Reaction: Biaryl Synthesis via Trapping Reactions between HDDA-Generated Benzynes and Phenolics
Benzynes produced thermally by the cycloisomerization of triyne-containing precursors [i.e., by the hexadehydro-Diels–Alder (HDDA) reaction] react with phenols at the carbon ortho to the hydroxyl in an ene-like fashion. Following tautomerization of the intermediate cyclohexadienones, this produces b...
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| Publicado no: | Org Lett |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5107112/ https://ncbi.nlm.nih.gov/pubmed/27767316 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02830 |
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