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A Heck-Matsuda Process for the Synthesis of β-Arylethenesulfonyl Fluorides: Selectively Addressable Bis-electrophiles for SuFEx Click Chemistry

A Heck-Matsuda process for the synthesis of the otherwise difficult to access compounds, β-arylethenesulfonyl fluorides, is described. Ethenesulfonyl fluoride (i.e., vinylsulfonyl fluoride, or ESF) undergoes β-arylation with stable and readily prepared arenediazonium tetrafluoroborates in the presen...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Qin, Hua-Li, Zheng, Qinheng, Bare, Grant A. L., Wu, Peng, Sharpless, K. Barry
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5102157/
https://ncbi.nlm.nih.gov/pubmed/27723200
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608807
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