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Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe(2)(S(3)CPh(2))(CO)(6)] and Related Complexes
The photochemical reaction of Fe(2)(S(2))(CO)(6) and Ph(2)CS affords the perthiolate Fe(2)(S(3)CPh(2))(CO)(6) (1) in good yield. As confirmed crystallographically, 1 contains a previously elusive perthiolate ligand. The related reaction of Fe(2)(S(2))(CO)(5)-(PPh(3)) and Ph(2)CS gave Fe(2)(S(3)CPh(2...
Shranjeno v:
| izdano v: | Eur J Inorg Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2016
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5089076/ https://ncbi.nlm.nih.gov/pubmed/27818613 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201600366 |
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