Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates

[Image: see text] Reported are complexes of the formula Fe(dithiolate)(CO)(2)(diphos) and their use to prepare homo- and heterobimetallic dithiolato derivatives. The starting iron dithiolates were prepared by a one-pot reaction of FeCl(2) and CO with chelating diphosphines and dithiolates, where dit...

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Detalhes bibliográficos
Main Authors: Carroll, Maria E., Chen, Jinzhu, Gray, Danielle E., Lansing, James C., Rauchfuss, Thomas B., Schilter, David, Volkers, Phillip I., Wilson, Scott R.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3999794/
https://ncbi.nlm.nih.gov/pubmed/24803716
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om400752a
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