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Cationic Si−H−Si Bridges in Polysilanes: Their Detection and Targeted Formation in Stable Ion Studies

The ionization of 1,1‐dihydridocyclopentasilane 7 has been found to yield the cyclic polysilanylsilyl cation 8 instead of the expected hydrogen‐substituted silylium ion 6. The silyl cation 8 is stabilized by the formation of an intramolecular Si−H−Si bridge, which also provides the thermodynamic dri...

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Vydáno v:Chemistry
Hlavní autoři: Albers, Lena, Baumgartner, Judith, Marschner, Christoph, Müller, Thomas
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2016
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5074309/
https://ncbi.nlm.nih.gov/pubmed/27105609
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201600116
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