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Conformational Control of Polysilanes: Use of CH(2) Spacers in the Silicon Backbone

[Image: see text] By the reaction of a number of oligosilyl potassium compounds with (trimethylsilyl)chloromethane, derivatives containing the (trimethylsilyl)methyl substituent were prepared. Using X-ray single-crystal structure analysis and UV spectroscopy the conformational properties of some of...

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Detalhes bibliográficos
Main Authors: Wallner, Andreas, Hlina, Johann, Wagner, Harald, Baumgartner, Judith, Marschner, Christoph
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2011
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3148124/
https://ncbi.nlm.nih.gov/pubmed/21818170
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om1011159
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