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New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks
Multisubstituted tropanes and indolizidines have been prepared with high regio- and stereoselectivity by the [3 + 2] cycloaddition of unstabilized azomethine ylides generated from readily prepared trimethylsilyl substituted 1,2-dihydropyridines via protonation or alkylation followed by desilylation....
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5066814/ https://ncbi.nlm.nih.gov/pubmed/27642766 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08355 |
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