Direct observation of light-driven, concerted electron–proton transfer

The phenols 4-methylphenol, 4-methoxyphenol, and N-acetyl-tyrosine form hydrogen-bonded adducts with N-methyl-4, 4′-bipyridinium cation (MQ(+)) in aqueous solution as evidenced by the appearance of low-energy, low-absorptivity features in UV-visible spectra. They are assigned to the known examples o...

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Bibliographic Details
Published in:Proc Natl Acad Sci U S A
Main Authors: Gagliardi, Christopher J., Wang, Li, Dongare, Prateek, Brennaman, M. Kyle, Papanikolas, John M., Meyer, Thomas J., Thompson, David W.
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2016
Subjects:
Physical Sciences
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5056112/
https://ncbi.nlm.nih.gov/pubmed/27660239
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1611496113
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