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Gd(III) and Mn(II) complexes for dynamic nuclear polarization: small molecular chelate polarizing agents and applications with site-directed spin labeling of proteins

We investigate complexes of two paramagnetic metal ions Gd(3+) and Mn(2+) to serve as polarizing agents for solid-state dynamic nuclear polarization (DNP) of (1)H, (13)C, and (15)N at magnetic fields of 5, 9.4, and 14.1 T. Both ions are half-integer high-spin systems with a zero-field splitting and...

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Detalhes bibliográficos
Publicado no:Phys Chem Chem Phys
Main Authors: Kaushik, Monu, Bahrenberg, Thorsten, Can, Thach V., Caporini, Marc A., Silvers, Robert, Heiliger, Jörg, Smith, Albert A., Schwalbe, Harald, Griffin, Robert G., Corzilius, Björn
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5053914/
https://ncbi.nlm.nih.gov/pubmed/27545112
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cp04623a
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