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Gd(III) and Mn(II) complexes for dynamic nuclear polarization: small molecular chelate polarizing agents and applications with site-directed spin labeling of proteins
We investigate complexes of two paramagnetic metal ions Gd(3+) and Mn(2+) to serve as polarizing agents for solid-state dynamic nuclear polarization (DNP) of (1)H, (13)C, and (15)N at magnetic fields of 5, 9.4, and 14.1 T. Both ions are half-integer high-spin systems with a zero-field splitting and...
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Publicado no: | Phys Chem Chem Phys |
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Main Authors: | , , , , , , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
2016
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5053914/ https://ncbi.nlm.nih.gov/pubmed/27545112 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6cp04623a |
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