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High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions

We report the dynamic nuclear polarization of (1)H spins in magic angle spinning spectra recorded at 5 T and 84K via the solid effect using Mn(2+) and Gd(3+) complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective linewidth of the centr...

詳細記述

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書誌詳細
主要な著者: Corzilius, Björn, Smith, Albert A., Barnes, Alexander B., Luchinat, Claudio, Bertini, Ivano, Griffin, Robert G.
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3086350/
https://ncbi.nlm.nih.gov/pubmed/21446700
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1109002
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