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High Field Dynamic Nuclear Polarization with High-Spin Transition Metal Ions
We report the dynamic nuclear polarization of (1)H spins in magic angle spinning spectra recorded at 5 T and 84K via the solid effect using Mn(2+) and Gd(3+) complexes as polarizing agents. We show that the magnitude of the enhancements can be directly related to the effective linewidth of the centr...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3086350/ https://ncbi.nlm.nih.gov/pubmed/21446700 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja1109002 |
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