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Identification of Mechanism-Based Inactivation in P450-Catalyzed Cyclopropanation Facilitates Engineering of Improved Enzymes

Following the recent discovery that heme proteins can catalyze the cyclopropanation of styrenyl olefins with high efficiency and selectivity, interest in developing new enzymes for a variety of non-natural carbene transfer reactions has burgeoned. The fact that diazo compounds and other carbene prec...

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Detaylı Bibliyografya
Yayımlandı:J Am Chem Soc
Asıl Yazarlar: Renata, Hans, Lewis, Russell D., Sweredoski, Michael J., Moradian, Annie, Hess, Sonja, Wang, Z. Jane, Arnold, Frances H.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2016
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5042878/
https://ncbi.nlm.nih.gov/pubmed/27573353
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b06823
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