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An unexpected Lewis acid catalyzed Diels-Alder cycloaddition of aryl allenes and acrylates

An unexpected [4+2] cycloaddition of aryl allenes and simple acrylate derivatives is reported. This process functions well with a variety of allenes and acrylates to generate bi- and tricyclic dihydronaphthalene derivatives through a nonconventional bond disconnection.

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Pubblicato in:Tetrahedron
Autori principali: Conner, Michael L., Brown, M. Kevin
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5038599/
https://ncbi.nlm.nih.gov/pubmed/27695139
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2016.02.028
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