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Palladium-Catalysis Enables Benzylation of α,α-Difluoroketone Enolates
S(N)1 and S(N)2-like alkylation reactions of ketone enolates with sp(3)-based electrophiles are essential transformations for generating α-substituted ketone products. However, alkylation reactions of weakly nucleophilic α,α-difluoroketone enolates with sp(3)-hybridized electrophiles remain nearly u...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4972046/ https://ncbi.nlm.nih.gov/pubmed/27312868 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201604149 |
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