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Diisopropylethylamine/hexafluoroisopropanol-mediated ion-pairing UHPLC-MS for phosphate and carboxylate metabolite analysis: utility for studying cellular metabolism

RATIONALE: Mass spectrometric (MS) analysis of low molecular weight polar metabolites can be challenging because of poor chromatographic resolution of isomers and insufficient ionization efficiency. These metabolites include intermediates in key metabolic pathways, such as glycolysis, the pentose ph...

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Detalhes bibliográficos
Publicado no:Rapid Commun Mass Spectrom
Main Authors: Guo, Lili, Worth, Andrew J., Mesaros, Clementina, Snyder, Nathaniel W., Glickson, Jerry D., Blair, Ian A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4970762/
https://ncbi.nlm.nih.gov/pubmed/27476658
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/rcm.7667
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