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Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones()
The asymmetric alkylation of acyclic ketones is a longstanding challenge in organic synthesis. We report diastereoselective and enantioselective allylic substitutions with acyclic α-alkoxy ketones catalyzed by a metallacyclic iridium complex to form products with contiguous stereogenic centers deriv...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4969080/ https://ncbi.nlm.nih.gov/pubmed/27038004 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600235 |
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