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HandaPhos. A general ligand enabling sustainable ppm levels of palladium-catalyzed cross-couplings in water at room temperature
A new monophosphine ligand, HandaPhos, has been identified that when complexed in a 1:1 ratio with Pd(OAc)(2), forms a catalyst that is generally useful, enabling Pd-catalyzed cross-couplings to be run using ≤1000 ppm of this catalyst. Applications to heavily utilized Suzuki-Miyaura reactions involv...
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| Pubblicato in: | Angew Chem Int Ed Engl |
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| Autori principali: | , , , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4966530/ https://ncbi.nlm.nih.gov/pubmed/26924396 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201510570 |
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