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Chemo- and Stereoselective Transition-Metal-Free Amination of Amides with Azides
[Image: see text] The synthesis of α-amino carbonyl/carboxyl compounds is a contemporary challenge in organic synthesis. Herein, we present a stereoselective α-amination of amides employing simple azides that proceeds under mild conditions with release of nitrogen gas. The amide is used as the limit...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
American Chemical
Society
2016
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| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4945995/ https://ncbi.nlm.nih.gov/pubmed/27350334 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04061 |
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