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Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F
The first biomimetic enantioselective total synthesis of (−)-communesin F based on a late-stage heterodimerization and aminal exchange is described. Our synthesis features the expedient diazene–directed assembly of two advanced fragments to secure the congested C3a–C3a′ linkage in three steps, follo...
Gardado en:
| Publicado en: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2016
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4944760/ https://ncbi.nlm.nih.gov/pubmed/27244250 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04072 |
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