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Ruthenium-BINAP Catalyzed Alcohol C-H tert-Prenylation via 1,3-Enyne Transfer Hydrogenation: Beyond Stoichiometric Carbanions in Enantioselective Carbonyl Propargylation
The chiral ruthenium complex formed in situ from (TFA)(2)Ru(CO)(PPh(3))(2) and (R)-BINAP is found to catalyze the enantioselective C-C coupling of diverse primary alcohols with the 1,3-enyne, TMSC≡CC(Me)=CH(2), to form secondary homopropargyl alcohols bearing gem-dimethyl groups. All reagents for th...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4920142/ https://ncbi.nlm.nih.gov/pubmed/27079149 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b02279 |
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