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A C–H bond activation-based catalytic approach to tetrasubstituted chiral allenes
Enantioselective synthesis of fully substituted allenes has been a challenge due to the non-rigid nature of the axial chirality, which spreads over three carbon atoms. Here we show the commercially available simple Rh complex may catalyse the CMD (concerted metalation/deprotonation)-based reaction o...
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| Publicado en: | Nat Commun |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
Nature Publishing Group
2015
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4918348/ https://ncbi.nlm.nih.gov/pubmed/26246391 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms8946 |
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