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Phosphine-Mediated Iterative Arene Homologation Using Allenes
A PPh(3)-mediated multicomponent reaction between o-phthalaldehydes, nucleophiles, and monosubstituted allenes furnishes functionalized non-C(2)-symmetric naphthalenes in synthetically useful yields. When the Co-phthalaldehydes were reacted with 1,3-disubstituted allenes in the presence of PPh(2)Et,...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4915745/ https://ncbi.nlm.nih.gov/pubmed/26295504 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b07403 |
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