Methane as a Selectivity Booster in the Arc‐Discharge Synthesis of Endohedral Fullerenes: Selective Synthesis of the Single‐Molecule Magnet Dy(2)TiC@C(80) and Its Congener Dy(2)TiC(2)@C(80)

The use of methane as a reactive gas dramatically increases the selectivity of the arc‐discharge synthesis of M‐Ti‐carbide clusterfullerenes (M=Y, Nd, Gd, Dy, Er, Lu). Optimization of the process parameters allows the synthesis of Dy(2)TiC@C(80)‐I and its facile isolation in a single chromatographic...

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Publicado en:Angew Chem Int Ed Engl
Autores principales: Junghans, Katrin, Schlesier, Christin, Kostanyan, Aram, Samoylova, Nataliya A., Deng, Qingming, Rosenkranz, Marco, Schiemenz, Sandra, Westerström, Rasmus, Greber, Thomas, Büchner, Bernd, Popov, Alexey A.
Formato: Artigo
Lenguaje:Inglês
Publicado: WILEY‐VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC4902133/
https://ncbi.nlm.nih.gov/pubmed/26350440
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201505870
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