Selective arc-discharge synthesis of Dy(2)S-clusterfullerenes and their isomer-dependent single molecule magnetism

A method for the selective synthesis of sulfide clusterfullerenes Dy(2)S@C(2n) is developed. Addition of methane to the reactive atmosphere reduces the formation of empty fullerenes in the arc-discharge synthesis, whereas the use of Dy(2)S(3) as a source of metal and sulfur affords sulfide clusterfu...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Chen, Chia-Hsiang, Krylov, Denis S., Avdoshenko, Stanislav M., Liu, Fupin, Spree, Lukas, Yadav, Ravi, Alvertis, Antonis, Hozoi, Liviu, Nenkov, Konstantin, Kostanyan, Aram, Greber, Thomas, Wolter, Anja U. B., Popov, Alexey A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5734629/
https://ncbi.nlm.nih.gov/pubmed/29263779
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc02395b
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