Synthesis and Isolation of the Titanium–Scandium Endohedral Fullerenes—Sc(2)TiC@I(h)‐C(80), Sc(2)TiC@D (5h)‐C(80) and Sc(2)TiC(2)@I(h)‐C(80): Metal Size Tuning of the Ti(IV)/Ti(III) Redox Potentials

The formation of endohedral metallofullerenes (EMFs) in an electric arc is reported for the mixed‐metal Sc–Ti system utilizing methane as a reactive gas. Comparison of these results with those from the Sc/CH(4) and Ti/CH(4) systems as well as syntheses without methane revealed a strong mutual influe...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Junghans, Katrin, Ghiassi, Kamran B., Samoylova, Nataliya A., Deng, Qingming, Rosenkranz, Marco, Olmstead, Marilyn M., Balch, Alan L., Popov, Alexey A.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Full Papers
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5029561/
https://ncbi.nlm.nih.gov/pubmed/27459520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201601655
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