Stereoselective amine-thiourea-catalysed sulfa-Michael/nitroaldol cascade approach to 3,4,5-substituted tetrahydrothiophenes bearing a quaternary stereocenter

An investigation on the stereoselective cascade sulfa-Michael/aldol reaction of nitroalkenes and commercially available 1,4-dithiane-2,5-diol to 3,4,5-substituted tetrahydrothiophenes, bearing a quaternary stereocenter, is presented. A secondary amine thiourea derived from (R,R)-1,2-diphenylethylami...

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Vydáno v:Beilstein J Org Chem
Hlavní autoři: Meninno, Sara, Volpe, Chiara, Della Sala, Giorgio, Capobianco, Amedeo, Lattanzi, Alessandra
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2016
Témata:
Letter
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4901985/
https://ncbi.nlm.nih.gov/pubmed/27340455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.63
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